ChemInform Abstract: Directed Intermolecular (4 + 2) Cycloaddition of Unactivated 1,3-Diene Substrates with High Regio- and Stereoselectivities.
β Scribed by M. MURAKAMI; K. ITAMI; Y. ITO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Directed Intermolecular (4 + 2) Cycloaddition of Unactivated 1,3-Diene Substrates with High Regio-and Stereoselectivities.
-Pd(0)-catalyzed cycloaddition of vinylallenes with ordinary 1,3-dienes leads to cyclohexene derivatives. High regio-and stereoselectivities are achieved under mild conditions without the aid of electron-withdrawing or -releasing substituents.
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