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ChemInform Abstract: Synthesis of 2,3,4-Triphenyl-3-azabicyclo[3.2.0]hepta-1,4-diene and Its Novel Reaction with Dimethyl Acetylenedicarboxylate.

โœ Scribed by K. MATSUMOTO; S. GOTO; N. HAYASHI; T. UCHIDA; A. KAKEHI


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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## Novel Conversion of Perfluoro(2,6-dimethyl-1-azacyclohexene) to 3,3,4,4,5-Pentafluoro-2,6-diphenyl-2,6-bis (trifluoromethyl)-1azabicyclo[3.1.0]hexane. -Treatment of perfluoro-azacyclohexene (I) with 2 equiv. of phenyllithium (V) in a cyclohexane/Et 2 O mixture provides access to azabicyclohex