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ChemInform Abstract: Relative Rate Constants for the Reactions of CF3OF with Olefins in Solution

โœ Scribed by W. NAVARRINI; A. RUSSO; V. TORTELLI


Book ID
112028174
Publisher
John Wiley and Sons
Year
2010
Weight
22 KB
Volume
27
Category
Article
ISSN
0931-7597

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Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21