ChemInform Abstract: Reduction of Oxindoles with Sodium Bis(2-methoxyethoxy)aluminum Hydride, a Novel Reducing Agent.
โ Scribed by X.-F. PEI; S. BI
- Book ID
- 112022703
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
A new reducing agent (2j) reduced the enone (4) to give 15(S)-allylic alcohol (5a) with excellent regio-and stereoselectivity through a five membered ring transition state. Stereoselectivity of this reaction will be explained based on the LUMO of the enone moiety. The resulting (5a) was led to a car
Stereoselective Reduction of Conjugated Homopropargylic Alcohols to (E) -Homoallylic Alcohols by Sodium Bis(2-methoxyethoxy) Aluminum Hydride. -An efficient and mild stereoselective reduction of homopropargylic alcohols to the corresponding (E)-homoallylic alcohols using Red-Al is reported. The met