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ChemInform Abstract: Stereoselective Reduction of Conjugated Homopropargylic Alcohols to (E) -Homoallylic Alcohols by Sodium Bis(2-methoxyethoxy) Aluminum Hydride.

✍ Scribed by B. CROUSSE; M. ALAMI; G. LINSTRUMELLE

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199751104

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✦ Synopsis

Stereoselective Reduction of Conjugated Homopropargylic Alcohols to (E) -Homoallylic Alcohols by Sodium Bis(2-methoxyethoxy) Aluminum Hydride.

-An efficient and mild stereoselective reduction of homopropargylic alcohols to the corresponding (E)-homoallylic alcohols using Red-Al is reported. The methodology can be applied to the synthesis of the diol ( XIII) present in various biologically active compounds.

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