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ChemInform Abstract: Radical Cyclization of Fluorinated 1,3-Dicarbonyl Compounds with Dienes Using Manganese(III) Acetate and Synthesis of Fluoroacylated 4,5-Dihydrofurans.

✍ Scribed by Mehmet Yilmaz; E. Vildan Burgaz Yilmaz; A. Tarik Pekel

Book ID
112042546
Publisher
John Wiley and Sons
Year
2012
Weight
36 KB
Volume
43
Category
Article
ISSN
0931-7597

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Radical Cyclization of Fluorinated 1,3-D
Radical Cyclization of Fluorinated 1,3-Dicarbonyl Compounds with Dienes Using Manganese(III) Acetate and Synthesis of Fluoroacylated 4,5-Dihydrofurans
✍ Mehmet Yılmaz; E. Vildan Burgaz Yılmaz; A. Tarık Pekel 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 214 KB

## Abstract Radical cyclizations of fluorinated 1,3‐dicarbonyl compounds with dienes mediated by Mn(OAc)~3~ afforded 4,5‐dihydrofurans containing difluoroacetyl, trifluoroacetyl, or heptafluorobutanoyl groups in good‐to‐excellent yields. Additionally, 2‐(difluoromethyl)‐4,5‐dihydrofurans and a 4,7‐