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Free Radical Cyclization of 1,3‐Dicarbonyl Compounds Mediated by Manganese(III) Acetate with Alkynes and Synthesis of Tetrahydrobenzofurans, Naphthalene, and Trifluoroacetyl Substituted Aromatic Compounds

✍ Scribed by Alagoz, Oguzhan; Yılmaz, Mehmet; Tarık Pekel, A.


Book ID
120517312
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
116 KB
Volume
36
Category
Article
ISSN
0039-7911

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Radical Cyclization of Fluorinated 1,3-D
✍ Mehmet Yılmaz; E. Vildan Burgaz Yılmaz; A. Tarık Pekel 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 214 KB

## Abstract Radical cyclizations of fluorinated 1,3‐dicarbonyl compounds with dienes mediated by Mn(OAc)~3~ afforded 4,5‐dihydrofurans containing difluoroacetyl, trifluoroacetyl, or heptafluorobutanoyl groups in good‐to‐excellent yields. Additionally, 2‐(difluoromethyl)‐4,5‐dihydrofurans and a 4,7‐