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ChemInform Abstract: Synthesis of Fluoroacylated 4,5-Dihydrofurans and Fluoroalkylated Tetrahydrofurans by the Radical Cyclization Using Manganese(III) Acetate. Part 2.

โœ Scribed by Mehmet Yilmaz; A. Tarik Pekel


Publisher
John Wiley and Sons
Year
2011
Weight
36 KB
Volume
42
Category
Article
ISSN
0931-7597

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Radical Cyclization of Fluorinated 1,3-D
โœ Mehmet Yฤฑlmaz; E. Vildan Burgaz Yฤฑlmaz; A. Tarฤฑk Pekel ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 214 KB

## Abstract Radical cyclizations of fluorinated 1,3โ€dicarbonyl compounds with dienes mediated by Mn(OAc)~3~ afforded 4,5โ€dihydrofurans containing difluoroacetyl, trifluoroacetyl, or heptafluorobutanoyl groups in goodโ€toโ€excellent yields. Additionally, 2โ€(difluoromethyl)โ€4,5โ€dihydrofurans and a 4,7โ€