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ChemInform Abstract: Preparation of Silyl Enol Ethers Derived from α-Phenylseleno Aldehydes and α-Phenylseleno Ketones.

✍ Scribed by S. PONTHIEUX; F. OUTURQUIN; C. PAULMIER


Book ID
112024460
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
26
Category
Article
ISSN
0931-7597

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Reaction of α-chloro-α-phenylselenoester
✍ Claudio C. Silveira; Antonio L. Braga; Alessandra Machado; Gustavo L. Fiorin; Mi 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 263 KB

Sly1 enol ethers of ketones are alkylated with ethyl a-chloro-a-phenylseleno acetate la or with ethyl a-chloro-a-phenylseleno propionate lb, mediated by zinc bromide to give the corresponding a-phenylseleno-y-keto esters 3 in moderate to good yields.