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ChemInform Abstract: Practical, Enantiospecific Syntheses of 14,15-EET and Leukotoxin B (Vernolic Acid).

✍ Scribed by J. R. Falck; Y. Krishna Reddy; Donovan C. Haines; Komandla Malla Reddy; U. Murali Krishna; Sandra Graham; Barbara Murry; Julian A. Peterson

Book ID
101925109
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Practical, enantiospecific syntheses of
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✍ J.R Falck; Y.Krishna Reddy; Donovan C Haines; Komandla Malla Reddy; U.Murali Kri πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 66 KB

Cytochrome P450BM3 and its F87V mutant were exploited for a convenient, laboratory scale (1 mmol) preparation of 14(S),15(R)-epoxyeicosatrienoic acid [14(S),15(R)-EET] from arachidonic acid and (+)-leukotoxin B [(+)-12(S),13(R)-vernolic acid] from linoleic acid, respectively. Their enantiomers were

ChemInform Abstract: Enantiospecific Syn
ChemInform Abstract: Enantiospecific Synthesis of (-)-5-epi-Shikimic Acid and (-)-Shikimic Acid.
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Enantiospecific Synthesis of (-)-5-epi-Shikimic Acid and (-)-Shikimic Acid. -The key step in the synthesis of the title compounds (XI) and (XVI) is the intramolecular cycloaddition of the nitrones (V) and (XIV). -