The optically active crotepoxide 1 and iso-crotepoxide 2 have been constructed from quinic acid involving a singlet oxygen photooxygentation as the key step. Recently, the chemotherapeutic potential of glycosidase inhibitors 1 as anti-HIV, 2 anti-metastasis, 3 and antihyperglycemic agents 4 has aro
โฆ LIBER โฆ
ChemInform Abstract: First Enantiospecific Syntheses of Crotepoxide and iso-Crotepoxide from (-)-Quinic Acid.
โ Scribed by T. K. M. SHING; E. K. W. TAM
- Book ID
- 112034086
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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## Hoi o i i ( ' ~i i i ~p i ~i ~m ~s 20 (!Vm wpp/wneni S(,rics V d . 54). Springer. Berlin, 1979. [ I l l " H (160.5 Mtlr). 'H (500.1 MHr). and "P (122 M H d NMR data (CDCI,. 25 ('. rel,iti\c intensities i n parentheses): 6("8) = + 46.7(1). + 46.3(1). ('ii + 1 3 1 I, + l0.7(1). -3.1(1) (resonance