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Enantiospecific Syntheses of (+)-Crotepoxide, (+)-Boesenoxide, (+)-β-Senepoxide, (+)-Pipoxide Acetate, (−)- iso -Crotepoxide, (−)-Senepoxide, and (−)-Tingtanoxide from (−)-Quinic Acid 1

✍ Scribed by Shing, Tony K. M.; Tam, Eric K. W.


Book ID
127114350
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
373 KB
Volume
63
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES


First enantiospecific syntheses of crote
✍ Tony K.M Shing; Eric K.W Tam 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 213 KB

The optically active crotepoxide 1 and iso-crotepoxide 2 have been constructed from quinic acid involving a singlet oxygen photooxygentation as the key step. Recently, the chemotherapeutic potential of glycosidase inhibitors 1 as anti-HIV, 2 anti-metastasis, 3 and antihyperglycemic agents 4 has aro