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Practical, enantiospecific syntheses of 14,15-EET and leukotoxin B (vernolic acid)

✍ Scribed by J.R Falck; Y.Krishna Reddy; Donovan C Haines; Komandla Malla Reddy; U.Murali Krishna; Sandra Graham; Barbara Murry; Julian A Peterson

Book ID
104230760
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
66 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cytochrome P450BM3 and its F87V mutant were exploited for a convenient, laboratory scale (1 mmol) preparation of 14(S),15(R)-epoxyeicosatrienoic acid [14(S),15(R)-EET] from arachidonic acid and (+)-leukotoxin B [(+)-12(S),13(R)-vernolic acid] from linoleic acid, respectively. Their enantiomers were accessed via a four-step chemical inversion.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Practical, Enantios
ChemInform Abstract: Practical, Enantiospecific Syntheses of 14,15-EET and Leukotoxin B (Vernolic Acid).
✍ J. R. Falck; Y. Krishna Reddy; Donovan C. Haines; Komandla Malla Reddy; U. Mural πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB

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