𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Photochemical Rearrangement of N-Mesyloxylactams: Stereospecific Formation of N-Heterocycles.

✍ Scribed by Alexandre Drouin; Dana K. Winter; Simon Pichette; Samuel Aubert-Nicol; Jean Lessard; Claude Spino

Publisher
John Wiley and Sons
Year
2011
Weight
32 KB
Volume
42
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Upon irradiation a number of N‐mesyloxylactams such as (I), (IV), (VI), and (VIII) undergo efficient ring‐contraction yielding pyrrolidine, piperidine, and azepane derivatives.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Photochemical Rearr
ChemInform Abstract: Photochemical Rearrangement of exo-3,6,7-Trioxatricyclo[3.2.2.02,4]nonane.
✍ N. I. KURBANOGLU; Y. KARA; H. SECEN; N. AKBULUT πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 1 views

## Photochemical Rearrangement of exo-3,6,7-Trioxatricyclo[3.2.2.0 2,4 ]nonane. -The photolysis of trioxatricyclononane (I) in the presence of dicyanoanthracene as sensitizer in methanol gives a mixture of nine products [e.g. (III)-(IX)]. The mechanism is discussed and compared with the results o