## Abstract Upon irradiation a number of Nβmesyloxylactams such as (I), (IV), (VI), and (VIII) undergo efficient ringβcontraction yielding pyrrolidine, piperidine, and azepane derivatives.
Regioselective Photochemical Rearrangement of N-Mesyloxylactams
β Scribed by Simon Pichette; Samuel Aubert-Nicol; Jean Lessard; Claude Spino
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 594 KB
- Volume
- 2012
- Category
- Article
- ISSN
- 1434-193X
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π SIMILAR VOLUMES
Rearrangement reactions are ubiquitous and they can occur both in the ground state as well as in the excited state. [1] The photochemical properties of stilbene-type compounds are well-documented [2Β±4] and major reactions include cis Β± trans isomerization, exciplex reactions, addition, and oxidative
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