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ChemInform Abstract: Phosphorylation of Phenols and Naphthols by Phenyl-methylenephosphine Oxide Generated by the Thermolysis of a 2-Phosphabicyclo[2.2.2]octa-5,7-diene 2-Oxide.

✍ Scribed by Gy. Keglevich; H. Szelke; A. Dobo; Z. Nagy; L. Toke


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
32
Category
Article
ISSN
0931-7597

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Generation of methylenephosphine oxides
✍ GyΓΆrgy Keglevich; KΓ‘lmΓ‘n ÚjszΓ‘szy; Louis D. Quin; GyΓΆngyi S. Quin πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 410 KB πŸ‘ 1 views

## Differential thermal analysis and differential scanning calorimetry showed that the title compounds decomposed at 240-260Β°C with release of the fragment RP(0) = CH,. Mass spectral studies also showed this to be a fragmentation pathway. The extruded methylenephosphine oxide could be trapped with