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Efficient Synthesis of Mixed Phosphonates by the Fragmentation-Related Phosphorylation of Alcohols Applying a 2-Phosphabicyclo[2.2.2]octa-5,7-diene 2-Oxide Precursor.

✍ Scribed by Helga Szelke; Krisztina Ludanyi; Timea Imre; Zoltan Nagy; Karoly Vekey; Laszlo Toeke; Gyoergy Keglevich


Publisher
John Wiley and Sons
Year
2005
Weight
16 KB
Volume
36
Category
Article
ISSN
0931-7597

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Generation of methylenephosphine oxides
✍ György Keglevich; Kálmán Újszászy; Louis D. Quin; Gyöngyi S. Quin 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 410 KB

## Differential thermal analysis and differential scanning calorimetry showed that the title compounds decomposed at 240-260°C with release of the fragment RP(0) = CH,. Mass spectral studies also showed this to be a fragmentation pathway. The extruded methylenephosphine oxide could be trapped with