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ChemInform Abstract: Phosphine-Catalyzed [3 + 2] Cycloaddition of Allenoates with Trifluoromethylketones: Synthesis of Dihydrofurans and Tetrahydrofurans.

✍ Scribed by Tong Wang; Song Ye

Publisher: John Wiley and Sons
Year: 2011
Weight: 28 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201149099

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## Abstract A new family of aspartic acid derivatives is obtained through cycloaddition reactions of oxazolones (I) with allenoate (II), providing restricted cyclopentanyl aspartic acid analogues (III) and (IV) under mild conditions.