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ChemInform Abstract: Triphenylphosphine-Catalyzed [3 + 2] Cycloaddition of Allenoate and Active Olefins: Synthesis of Spirooxindole Derivatives.

✍ Scribed by Shanyan Guo; Rendong Wang; Jian Li; Chunju Li; Hongmei Deng; Xueshun Jia

Publisher: John Wiley and Sons
Year: 2012
Weight: 36 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201205128

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Silver Hexafluoroantimonate-Catalyzed Th

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## Abstract The intermolecular [2+2+1] multicomponent cycloadditions from readily available allenoates, dual activated olefins and isocyanides catalyzed by silver hexafluoroantimonate were studied. This protocol allowed the syntheses of highly functionalized five‐membered carbocycles with exclusive