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ChemInform Abstract: Pheromone Synthesis. Part 193. Simple Synthesis of (.+-.)-Stigmolone (8-Hydroxy-2,5,8-trimethyl-4-nonanone), the Pheromone of Stigmatella aurantiaca.

✍ Scribed by Kenji Domon; Kenji Mori

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199930245

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✦ Synopsis

Pheromone Synthesis. Part 193. Simple Synthesis of (±)-Stigmolone (8-Hydroxy-2,5,8-trimethyl-4-nonanone), the Pheromone of Stigmatella aurantiaca. -Stigmolone (VIII), which induces the formation of the fruiting body of S. aurantiaca, is synthesized from ketone (I) in 48% overall yield in four steps. -(DOMON, KENJI; MORI, KENJI; Eur. J. Org. Chem.

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