ChemInform Abstract: First Asymmetric Synthesis of Stigmolone: The Fruiting Body Inducing Pheromone of the Myxobacterium Stigmatella aurantiaca.
โ Scribed by Dieter Enders; Andre Ridder
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 30 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Pheromone Synthesis. Part 193. Simple Synthesis of (ยฑ)-Stigmolone (8-Hydroxy-2,5,8-trimethyl-4-nonanone), the Pheromone of Stigmatella aurantiaca. -Stigmolone (VIII), which induces the formation of the fruiting body of S. aurantiaca, is synthesized from ketone (I) in 48% overall yield in four steps.
The enantiomers of the title compound 1 were synthesized bacterium Stigmatella aurantiaca at a concentration of 0.4ฯช1.0 nM. from the enantiomers of citronellol (2). Both (R)-and (S)-1 induced the formation of the fruiting body of a myxo-
Asymmetric Total Synthesis of the Caribbean Fruit Fly Pheromone (+)-Epianastrephin. -The chiral title compound (XI) is synthesized from the chiral benzamide (I) in 15 steps and 9.5% overall yield and ยฟ 98% enantiomeric excess. -(SCHULTZ, A.