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Synthesis of the Enantiomers of 8-Hydroxy-2,5,8-trimethyl-4-nonanone, the Myxobacterial Pheromone of Stigmatella aurantiaca to Induce the Formation of Its Fruiting Body

โœ Scribed by Kenji Mori; Motonobu Takenaka


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
121 KB
Volume
1998
Category
Article
ISSN
1434-193X

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โœฆ Synopsis


The enantiomers of the title compound 1 were synthesized bacterium Stigmatella aurantiaca at a concentration of 0.4ฯช1.0 nM. from the enantiomers of citronellol (2). Both (R)-and (S)-1 induced the formation of the fruiting body of a myxo-


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ChemInform Abstract: Pheromone Synthesis
โœ Kenji Domon; Kenji Mori ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB

Pheromone Synthesis. Part 193. Simple Synthesis of (ยฑ)-Stigmolone (8-Hydroxy-2,5,8-trimethyl-4-nonanone), the Pheromone of Stigmatella aurantiaca. -Stigmolone (VIII), which induces the formation of the fruiting body of S. aurantiaca, is synthesized from ketone (I) in 48% overall yield in four steps.