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ChemInform Abstract: Pheromone Synthesis. Part 178. Synthesis of (-)-exo-Isobrevicomin and Its (-)-endo Isomer, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae.

✍ Scribed by K. MORI; H. TAKIKAWA; Y. NISHIMURA; H. HORIKIRI

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract (–)‐__exo__‐Isobrevicomin {(1__S__,5__R__,7__S__)‐(–)‐5‐ethyl‐7‐methyl‐6,8‐dioxabicyclo[3.2.1]octane (1)} and its (–)‐__endo__ isomer [(1__S__,5__R__,7__R__)‐2] were synthesized by employing the acetylenic acetal 7 as the common intermediate and by using the Sharpless asymmetric dihydro

ChemInform Abstract: Pheromone Synthesis
ChemInform Abstract: Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)- and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae.
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Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)-and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae. -Both title compounds (V) and (VI) are synthesized via asymmetric dihydroxylation as the key ste

Pheromone Synthesis, CLXXXIII. Synthesis
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## Abstract Both (1__R__)‐ and (1__S__)‐hydroxy derivatives of (+)‐exo‐brevicomin {(1__R__,1′__R__,5′__R__,7′__R__)‐1‐(5′‐methyl‐6′,8′‐dioxabicyclo[3.2.1]‐octyl)ethanol (1) and its (1__S__)‐isomer (2)} were synthesized by employing Sharpless asymmetric dihydroxylation as the key reaction.