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Pheromone Synthesis, CLXXXIII. Synthesis of (1R,2R,5S,7R)- and (1R,2S,5S,7R)-2-hydroxy-exo-Brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle,dendroctonus ponderosae

✍ Scribed by Takikawa, Hirosato ;Shimbo, Ken-Ichiro ;Mori, Kenji

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
441 KB
Volume
1997
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

Both (2__R__)‐ and (2__S__)‐hydroxy derivatives of (+)‐exo‐brevicomin {5‐methyl‐6,8‐dioxabicyclo[3.2.1]octan‐2‐ol; 1 and 2} were synthesized by employing Sharpless asymmetric dihydroxylation as the key reaction.

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