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Novel Bicyclic Donors for the Synthesis of 2-Deoxy-β-glycosides. -Treatment of the novel heterocyclic donors (V) with a variety of alcohols in the presence of TfOH results in formation of β-glycosides with excellent stereoselectivity. Subsequent desulfurization with Raney-Ni efficiently gives 2-deo
Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides. -Using S-(2-deoxyglycosyl)phosphorodithioates such as (I) as glycosyl donors allows a highly diastereoselective synthesis of 2-deoxyα-glycosides [cf. (III)] and α-disaccharides such as (V). -(BIELAWSKA,
## Abstract The reaction of benzoic acids substituted with strong electron‐donating groups at the 2,4‐ or 2,6‐ position succeeds with high yields in a short times.