1999 carbohydrates carbohydrates U 0500 47 -218 2-Deoxy-2-iodo-α-mannopyranosyl and -talopyranosyl Acetates: Highly Stereoselective Glycosyl Donors for the Synthesis of 2-Deoxyα-glycosides. -Reactions of the title compounds with various glycosyl acceptors in the presence of TmsOTf are found to yiel
✦ LIBER ✦
ChemInform Abstract: Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides.
✍ Scribed by Halszka Bielawska; Maria Michalska
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides.
-Using S-(2-deoxyglycosyl)phosphorodithioates such as (I) as glycosyl donors allows a highly diastereoselective synthesis of 2-deoxyα-glycosides [cf. (III)] and α-disaccharides such as (V). -(BIELAWSKA,
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