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ChemInform Abstract: Novel Bicyclic Donors for the Synthesis of 2-Deoxy-β-glycosides.

✍ Scribed by R. W. FRANCK; C. H. MARZABADI

Publisher
John Wiley and Sons
Year
2010
Weight
44 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Novel Bicyclic Donors for the Synthesis of 2-Deoxy-β-glycosides.

-Treatment of the novel heterocyclic donors (V) with a variety of alcohols in the presence of TfOH results in formation of β-glycosides with excellent stereoselectivity. Subsequent desulfurization with Raney-Ni efficiently gives 2-deoxy-β-glycosides. This method can be used successfully to the synthesis of glycosidic linkages found in aureolic acid antibiotics. -(FRANCK, R. W.;

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