ChemInform Abstract: Palladium Catalyzed γ-Addition of Pronucleophiles to Allenyl Sulfides.
✍ Scribed by Y. YAMAMOTO; M. AL-MASUM; A. TAKEDA
- Book ID
- 112035587
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Palladium Catalyzed Addition of Carbon Pronucleophiles to Conjugated Enynes. -A new, catalytic route to the synthesis of differently substituted allenes is developed by addition of cyano-based carbon nucleophiles to conjugated enynes. Pd2(dba)3•CHCl3/dppf is found to be the best catalytic system fo