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ChemInform Abstract: Palladium Catalyzed Pronucleophile Addition to Unactivated Carbon—Carbon Multiple Bonds

✍ Scribed by Yoshinori Yamamoto; Ukkiramapandian Radhakrishnan

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium Catalyzed
ChemInform Abstract: Palladium Catalyzed Addition of Carbon Pronucleophiles to Conjugated Enynes.
✍ V. GEVORGYAN; C. KADOWAKI; M. M. SALTER; I. KADOTA; S. SAITO; Y. YAMAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

Palladium Catalyzed Addition of Carbon Pronucleophiles to Conjugated Enynes. -A new, catalytic route to the synthesis of differently substituted allenes is developed by addition of cyano-based carbon nucleophiles to conjugated enynes. Pd2(dba)3•CHCl3/dppf is found to be the best catalytic system fo