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ChemInform Abstract: Palladium-Catalyzed Cyanation of Carbon—Carbon Triple Bonds under Aerobic Conditions.

✍ Scribed by Shigeru Arai; Takashi Sato; Yuka Koike; Michino Hayashi; Atsushi Nishida

Publisher
John Wiley and Sons
Year
2009
Weight
66 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Palladium-Catalyzed Cyanation of CarbonC
Palladium-Catalyzed Cyanation of CarbonCarbon Triple Bonds Under Aerobic Conditions
✍ Shigeru Arai; Takashi Sato; Yuka Koike; Michino Hayashi; Atsushi Nishida 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 321 KB 👁 1 views

## Abstract **Essential oxygen**: The title transformation involves two different modes of cyanation, __syn__ and __anti__ cyanopalladation, as the key steps in this catalytic reaction. These processes enable successful dicyanative cyclization of diyne and enyne derivatives (see scheme).magnified i