Palladium-Catalyzed Cyanation of CarbonCarbon Triple Bonds Under Aerobic Conditions
β Scribed by Shigeru Arai; Takashi Sato; Yuka Koike; Michino Hayashi; Atsushi Nishida
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 321 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0044-8249
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β¦ Synopsis
Abstract
Essential oxygen: The title transformation involves two different modes of cyanation, syn and antiβ cyanopalladation, as the key steps in this catalytic reaction. These processes enable successful dicyanative cyclization of diyne and enyne derivatives (see scheme).magnified image
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