ChemInform Abstract: Palladium-Catalyzed Asymmetric Allylic Substitution Using Phosphoramidite Ligands Bearing 1,1′-Binaphthyl Skeleton.
✍ Scribed by Yongguang Gao; Xinsheng Li; Weiyi Chen; Dongcheng Xu
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 26 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-