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ChemInform Abstract: One-Pot Transformation of Glycopyranosylcyanides to N-(t-Butoxycarbonyl)methylamines.

✍ Scribed by Dirk H. Lenz; Gillian E. Norris; Carol M. Taylor; George C. Slim

Book ID
101918669
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
32
Category
Article
ISSN
0931-7597

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One-pot transformation of glycopyranosyl
One-pot transformation of glycopyranosylcyanides to N-(t-butoxycarbonyl)methylamines
✍ Dirk H Lenz; Gillian E Norris; Carol M Taylor; George C Slim πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 98 KB

Protected glycopyranosylcyanides were transformed into the corresponding N-tert-butoxycarbonyl-glycopyranosyl methylamines in a one-pot transformation in high yields. This general method is applicable to glycopyranosylcyanides bearing common O-and N-protecting groups frequently used in carbohydrate

ChemInform Abstract: Studies on the Tran
ChemInform Abstract: Studies on the Transformation of Azido-Group to N-(t-Butoxycarbonyl)amino Group via Staudinger Reaction.
✍ C. A. M. AFONSO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

Studies on the Transformation of Azido-Group to N-(t-Butoxycarbonyl)amino Group via Staudinger Reaction. -A simple and convenient method for the direct conversion of primary azides into N-Boc-amines [cf. (III), (V), (VII)] via iminophosphorane intermediates is described. The formation of symmetrica