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ChemInform Abstract: New Syntheses of Benzotriazepines by Non-Convenient Cyclization Reaction of N1,N3-Diarylamidrazones.

โœ Scribed by P. FROHBERG; P. NUHN

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

New Syntheses of Benzotriazepines by Non-Convenient Cyclization Reaction of N1,N3-Diarylamidrazones.

-The reaction of the N3-unsubstituted amidrazone (I) with formaldehyde gives the triazole (III). The corresponding N3-monosubstituted analogues (IV) yield the expected triazolines (V). Surprisingly, the amidrazones (VI) give the benzotriazepines (VII) under the same conditions.

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