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ChemInform Abstract: New Syntheses of Aryl Isothiocyanates from N-Arylimino-1,2,3- dithiazoles.

โœ Scribed by T. BESSON; J. GUILLARD; C. W. REES; M. THERISOD


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: New Syntheses of Ar
โœ T. BESSON; J. GUILLARD; C. W. REES; V. THIERY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB

New Syntheses of Aryl Isothiocyanates. -A new method for converting arylamines (II) into isothiocyanates based on the cleavage of stable arylimino-1,2,3-dithiazoles (III) is accomplished. EtMgBr and NaH prove to be appropriate reagents for this transformation. The cleavage proceeds via isolable cya