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ChemInform Abstract: New Practical Syntheses of 4′-Methylbiphenyl-2-carbonitrile and -2-carbaldehyde.

✍ Scribed by Dominique Goubet; Pascal Meric; Jean-Robert Dormoy; Patrice Moreau

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

New Practical Syntheses of 4'-Methylbiphenyl-2-carbonitrile and -2-carbaldehyde.

-A simple and efficient synthesis of the title biphenyl-carbonitrile (V) and carbaldehyde (III) is presented, involving the Mn-catalyzed nucleophilic aromatic substitution of commercially available ochlorobenzaldimine (I) with Grignard reagent (II) as key step. -(GOUBET,

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