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ChemInform Abstract: Na3AsSe3 and K3AsSe3 — Synthesis and Crystal Structure.

✍ Scribed by W. BRONGER; A. DONIKE; D. SCHMITZ

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Dimeric and Polymer
ChemInform Abstract: Dimeric and Polymeric Pnictidostannate(IV) Anions — Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3].
✍ M. ASBRAND; B. EISENMANN; H. ENGELHARDT; U. ROESSLER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

The title compounds are prepared from melts of mixtures of the elements. The isotypic [SnP 3 ] compounds crystallize in the orthorhombic system (space group Cmca, Z = 8) as determined by single crystal XRD, and contain dimeric [Sn 2 P 6 ] 10-anions formed by edge-sharing of two SnP 4 tetrahedra. Na