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ChemInform Abstract: K3SbSe3, Rb3SbSe3, and Cs3SbSe3 — Synthesis and Crystal Structure.

✍ Scribed by W. Bronger; A. Donike; D. Schmitz


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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K3SbSe3, Rb3SbSe3 und Cs3SbSe3 – Synthes
✍ W. Bronger; A. Donike; D. Schmitz 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 61 KB 👁 1 views

The compounds K 3 SbSe 3 , Rb 3 SbSe 3 and Cs 3 SbSe 3 were synthesized by heating mixtures of Sb 2 O 3 and an alkalicarbonate in a stream of hydrogen saturated by selenium in a temperature range between 750 °C and 800 °C. The compounds crystallize isostructural with Na 3 AsS 3 . A comparison of ato