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ChemInform Abstract: Metal-Free Uncatalyzed Reduction of α,β-Unsaturated Ketones Mediated by Hantzsch 1,4-Dihydropyridine.

✍ Scribed by Hua-Jian Xu; You-Cheng Liu; Yao Fu

Book ID
111699764
Publisher
John Wiley and Sons
Year
2008
Weight
27 KB
Volume
39
Category
Article
ISSN
0931-7597

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Copper(I) Salt Mediated 1,4-Reduction of α,β-Unsaturated Ketones Using Hydrosilanes. -The title reaction is carried out for several acyclic and cyclic α,β-unsaturated ketones in excellent yields. Sterically congested enones such as (Va) are recovered unchanged, a fact that can be applied in competit