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ChemInform Abstract: Conjugate Reduction of α,β-Unsaturated Ketones with Hydrosilane Mediated by Copper(I) Salt.

✍ Scribed by Atsunori Mori; Akinori Fujita; Hiroshi Kajiro; Yasushi Nishihara; Tamejiro Hiyama

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Copper(I) Salt Medi
ChemInform Abstract: Copper(I) Salt Mediated 1,4-Reduction of α,β-Unsaturated Ketones Using Hydrosilanes.
✍ A. MORI; A. FUJITA; Y. NISHIHARA; T. HIYAMA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Copper(I) Salt Mediated 1,4-Reduction of α,β-Unsaturated Ketones Using Hydrosilanes. -The title reaction is carried out for several acyclic and cyclic α,β-unsaturated ketones in excellent yields. Sterically congested enones such as (Va) are recovered unchanged, a fact that can be applied in competit