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ChemInform Abstract: Metal Complexes of Biologically Important Ligands. Part 105. Catalytic Formation of Oligopeptides from α-Amino Acid Esters with (p-Cymene)ruthenium(II) Complexes.

✍ Scribed by W. HOFFMUELLER; M. MAURUS; K. SEVERIN; W. BECK


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✍ Winfried Hoffmüller; Michael Maurus; Kay Severin; Wolfgang Beck 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 384 KB

Consecutive addition of one-equivalent portions of glycine ethyl ester to [(p-cymene)Ru(GGGOMeϪH + )Cl] leads to considerable amounts of (tetra-to nonapeptide)ruthenium complexes in a one-pot reaction, in which the (p-cymene)RuCl fragment acts as a catalyst. The analogous reaction with ala-