ChemInform Abstract: Metal Complexes of Biologically Important Ligands. Part 117. Addition of the O′Donnell Reagent [Ph2C=NCHCO2Me]- to Coordinated, Unsaturated Hydrocarbons of [(C6H7)Fe(CO)3]+, [C7H9Fe(CO)3]+, [(C7H7)M(CO)3]+ (M: Cr, Mo), and [(C2H4)Re(CO)5]+. α-Amino Acids with Organometallic Side Chains.

Addition des O'Donnell Reagenzes [Ph2C=N

Addition des O'Donnell Reagenzes [Ph2C=NCHCO2Me]– an π-koordinierte, ungesättigte Kohlenwasserstoffe in [(C6H7)Fe(CO)3]+, [(C7H9)Fe(CO)3]+, [(C7H7)M(CO)3]+ (M = Cr, Mo) und [(C2H4)Re(CO)5]+. α-Aminosäuren mit metallorganischen Seitenketten

✍ Theodor Ederer; Karlheinz Sünkel; Wolfgang Beck 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 126 KB 👁 1 views

The addition of [Ph 2 C=NCHCO 2 Me] ± to [(C 6 H 7 )Fe(CO) 3 ] + , [(C 7 H 9 )Fe(CO) 3 ] + , [(C 7 H 7 )M(CO) 3 ] + (M = Cr, Mo) and [(C 2 H 4 )Re(CO) 5 ] + gives derivatives of aamino acids with organometallic side chains. The structure of [(g 4 -C 6 H 7 )CH(N=CPh 2 )CO 2 Me]Fe(CO) 3 was determined