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ChemInform Abstract: [M3V18O42(H2O)12 (XO4)]×24H2O (M: Fe, Co; X: V, S): Metal Oxide Based Framework Materials Composed of Polyoxovanadate Clusters.

✍ Scribed by M. Ishaque Khan; Elizabeth Yohannes; Robert J. Doedens

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

V 18 O 42 (H 2 O) 12 (XO 4 )]•24H 2 O (M: Fe, Co; X: V, S): Metal Oxide Based Framework Materials Composed of Polyoxovanadate Clusters.

-The title compounds are characterized by single crystal XRD, FT-IR spectroscopy, thermal methods, and manganometric titration of the reduced V IV sites. The compounds have highly symmetrical, isomorphous structures (cubic, space group Im3m, Z = 2) that contain V IV /V V mixed-valent [V 18 O 42 (XO 4 )] clusters (X: V, S) linked by bridging M(H 2 O) 4 groups. -(

📜 SIMILAR VOLUMES

[M3V18O42(H2O)12(XO4)]⋅24 H2O (M = Fe, C
[M3V18O42(H2O)12(XO4)]⋅24 H2O (M = Fe, Co; X = V, S): auf Metalloxiden basierende Gerüste aus Polyoxovanadatclustern
✍ M. Ishaque Khan; Elizabeth Yohannes; Robert J. Doedens 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 112 KB

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ChemInform Abstract: Vanadium Oxide Clus
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