ChemInform Abstract: Vanadium Oxide Clusters as Building Blocks for the Synthesis of Metal Oxide Surfaces and Framework Materials: Synthesis and X-Ray Crystal Structure of [H6Mn3VIV15V v4O46(H2O)12] ×30H2O.

✍ Scribed by M. Ishaque Khan; Elizabeth Yohannes; Douglas Powell

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 41 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199916026

✦ Synopsis

Vanadium Oxide Clusters as Building Blocks for the Synthesis of Metal Oxide Surfaces and Framework Materials: Synthesis and X-Ray Crystal Structure of [

-Single crystal XRD results for the novel mixed-metal oxide of title, (III), reveal a three-dimensional framework structure composed of transition metal building blocks (cubic, space group Pn3, Z = 2). The extended structure consists of spheres of V 19 O 46 clusters, each linked by six µ 2 -Mn(H 2 O) 4 bridges thus forming a complex framework with tunnels and cavities occupied by lattice water molecules.

-(KHAN, M. ISHAQUE; YOHANNES, ELIZABETH;