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ChemInform Abstract: Ln4B4O11F2 (Ln: Eu, Dy): New Phases Isotypic to the Fluoride Borate Gd4B4O11F2

✍ Scribed by Almut Pitscheider; Michael Enders; Hubert Huppertz


Book ID
102054492
Publisher
John Wiley and Sons
Year
2011
Weight
20 KB
Volume
42
Category
Article
ISSN
0931-7597

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new title compound are obtained from a mixture of La2O3, B2O3, and LaF3 in the molar ratio 5:6:2 (Walker-type multianvil apparatus, 6 GPa, 1300 Β°C, 10 min). La4B4O11F2 crystallizes in the monoclinic space group P21/c with Z = 8. The crystal structure contains BO3 groups connected by BO4 tetrahedra v

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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 Β°C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4β€’H2O. The isostructural compounds crystallize in the m