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ChemInform Abstract: Iridium-Difluorphos-Catalyzed Asymmetric Hydrogenation of 2-Alkyl- and 2-Aryl-Substituted Quinoxalines: A General and Efficient Route into Tetrahydroquinoxalines.

✍ Scribed by Damien Cartigny; Takuto Nagano; Tahar Ayad; Jean-Pierre Genet; Takashi Ohshima; Kazushi Mashima; Virginie Ratovelomanan-Vidal

Book ID
102054007
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
42
Category
Article
ISSN
0931-7597

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Iridium-Difluorphos-Catalyzed Asymmetric
Iridium-Difluorphos-Catalyzed Asymmetric Hydrogenation of 2-Alkyl- and 2-Aryl-Substituted Quinoxalines: A General and Efficient Route into Tetrahydroquinoxalines
✍ Damien Cartigny; Takuto Nagano; Tahar Ayad; Jean-Pierre Genêt; Takashi Ohshima; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB 👁 1 views

## Abstract A highly efficient and general iridium‐difluorphos‐catalyzed asymmetric hydrogenation of diverse 2‐alkyl‐ and 2‐aryl‐substituted quinoxalines into biologically and pharmaceutically relevant 2‐substituted‐1,2,3,4‐tetrahydroquinoxaline units has been developed. High isolated yields and ex