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ChemInform Abstract: Intramolecular Reactivity of Triplet Carbonylcarbenes.

✍ Scribed by J. FIEN; W. KIRMSE


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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Intramolecular Reactivity of Triplet Car
✍ Johannes Fien; Wolfgang Kirmse πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 114 KB

Through a double cyclization triplet carbonylcarbenes add smoothly to double bonds in the Ξ΄ and Ξ΅ position, but do not react intramolecularly with C-H bonds (see scheme). The addition reaction fails if the keto group is replaced with an ester group.