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Intramolecular Reactivity of Triplet Carbonylcarbenes

✍ Scribed by Johannes Fien; Wolfgang Kirmse

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 114 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980904)37:16<2232::aid-anie2232>3.0.co;2-2

No coin nor oath required. For personal study only.

✦ Synopsis

Through a double cyclization triplet carbonylcarbenes add smoothly to double bonds in the δ and ε position, but do not react intramolecularly with C-H bonds (see scheme). The addition reaction fails if the keto group is replaced with an ester group.

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