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ChemInform Abstract: Intramolecular Reactivity of Functionalized Arylcarbenes: 1-(Hydroxymethyl)-9-fluorenylidene.

โœ Scribed by W. KIRMSE; B. KRZOSSA

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reactivity of Functionalized Arylcarbenes. 2-Phenylethyl Side Chains and Hetero Analogues.
โœ W. KIRMSE; W. KONRAD; I. S. OEZKIR ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 1 views

Reactivity of Functionalized Arylcarbenes. 2-Phenylethyl Side Chains and Hetero Analogues. -From the diazo precursors (I)-(III) the corresponding phenylcarbenes are generated thermally and photolytically. Stereorandom insertion reactions and large kinetic deuterium isotope effects point to a tripl