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ChemInform Abstract: Hydroacylation of 1-Alkene with Heteroaromatic Aldehyde by Rh(I) and Additives.

โœ Scribed by C.-H. JUN; D.-Y. LEE; J.-B. HONG

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Chelation-Assisted
ChemInform Abstract: Chelation-Assisted Intermolecular Hydroacylation: Direct Synthesis of Ketone from Aldehyde and 1-Alkene.
โœ C.-H. JUN; H. LEE; J.-B. HONG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The work describes a general direct intermolecular hydroacylation -not reported so far -of 1-alkene with aldehyde using the cocatalyst system of the transition metal complex and 2-amino-3-picoline. Some other metal complexes are also catalytically active. Without the addition of the picoline derivat